It felt like summer on that first beautiful 
Sunday of the new year out on the flats digging clams. The flats were 
littered with deposits of old clam and mussel shells, spiraled remnants 
of periwinkles and moon snails. Hard-shelled barnacles, still alive, 
encrusted the crumbling shells. Digging into the mud often involved 
working through thick layers of clam shells, layer upon layer, marking 
the passage of time.
The balmy temperatures 
and the shells got me thinking about one of the many changes to our 
world that is being driven by increased carbon dioxide emissions: ocean 
acidification.
Reports on ocean acidification 
have become fairly regular features in the science sections of 
newspapers lately, primarily because of new research into the 
intricacies of marine chemistry and the effects of increasing 
atmospheric carbon dioxide on marine life. We all have heard that 
atmospheric carbon dioxide has been increasing due to the burning of 
fossil fuels; a large part of this, almost one-third of the carbon 
dioxide emitted globally, is absorbed by the worlds' oceans.
Once
 it enters the ocean, the carbon dioxide reacts with water to produce 
carbonic acid. This is what causes ocean acidification. Organisms that 
live in the ocean and have shells or skeletons made out of calcium 
carbonate (barnacles, clams, a number of types of plankton and coral, 
for example) can have trouble getting enough carbonate for their shells 
if the water is too acidic. In fact, if the water becomes too acidic 
there can be so little carbonate that shells will start to dissolve.
This
 has happened before: 55 million years ago there was a period of global 
warming driven by increased atmospheric carbon dioxide. There are no 
fossils of microorganisms with calcium carbonate shells found in ocean 
sediments from that period, indicating that the sea water had become 
sufficiently acidic to keep these organisms from forming shells. (Nature
 March 2011).
It is quite worrisome that ocean
 acidification is believed to be progressing at least 10 times faster 
today than it did 55 million years ago.
While most studies point to the negative impacts 
of ocean acidification on marine life, the findings aren't all doom and 
gloom. One recent study out of Scripps Institute of Oceanography showed 
that pH (a measure of acidity) is highly variable throughout the world's
 oceans, and some places, like coral reefs, can become quite acidic as 
part of a daily cycle with no apparent ill effect on local residents. 
Other studies have found that different species differ in their ability 
to tolerate acidic, carbonate-deprived water.
In
 fact, two populations of the same species of spider crab were found to 
vary in their sensitivity to acidic waters. The more northern population
 was more sensitive; the southern population less so.
The
 take-home message from these studies is that the sea is one complicated
 kettle of fish; we currently don't fully understand marine chemistry, 
much less the impact of significantly changing that chemistry through 
our obsession with fossil fuels. The barnacles and clams and mussels 
must all hope that we stop what we are doing to the oceans soon enough 
to save them. I certainly do.
Sue Pike of York
 has worked as a researcher and a teacher in biology, marine biology and
 environmental science for years. 
 
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